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Vinyl sulfones (???-unsaturated sulfones) are productive and widely used intermediates in organic synthesis that also have a remarkable biomedical significance owed to their capability to act as irreversible inhibitors of many types of cysteine proteases through conjugate addition of the thiol group of the active site cysteine residue. This feature is the basis of some modern applications of this chemical function to Proteomics. Currently, there exists a solid body of knowledge on the chemical reactivity of the vinyl sulfone that allows the functionalization of any organic substrate.

 

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